Chemical equilibrium controlled synthesis of polyoxymethylene dimethyl ethers over sulfated titania
نویسندگان
چکیده
منابع مشابه
Low-Temperature Oxidation of Dimethyl Ether to Polyoxymethylene Dimethyl Ethers over CNT-Supported Rhenium Catalyst
Due to its excellent conductivity, good thermal stability and large specific surface area, carbon nano-tubes (CNTs) were selected as support to prepare a Re-based catalyst for dimethyl ether (DME) direct oxidation to polyoxymethylene dimethyl ethers (DMMx). The catalyst performance was tested in a continuous flow type fixed-bed reactor. H3PW12O40 (PW12) was used to modify Re/CNTs to improve its...
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Sulfated titania nanoparticles (SO42-/TiO2 NPs) were synthesized using titanium tetraisopropoxide (TTIP) by the sol-gel method. The structure and morphology of the prepared nanocatalyst was characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM) and Brunauer–Emmett–Teller (BET) methods as well as Fourier transform infrared (FT-IR) and energy dispersive X-ray (EDX) spectr...
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Nano sulfated titania was tested as solid acid heterogeneous catalyst for the synthesis of 4-(Trifluoromethyl) coumarin and coumarin derivatives under solvent-free condition. Factorial design evidenced a positive effect of reaction temperature, amount of catalyst, and solvents. This nano-sized sulfated titania has been prepared by a sol-gel hydrothermal process. The prepared sulfated titania s...
متن کاملSynthesis of 4-(trifluoromethyl) coumarins using nano sulfated-titania as solid acid catalyst under solvent-free conditions
Nano sulfated titania was tested as solid acid heterogeneous catalyst for the synthesis of 4-(Trifluoromethyl) coumarin and coumarin derivatives under solvent-free condition. Factorial design evidenced a positive effect of reaction temperature, amount of catalyst, and solvents. This nano-sized sulfated titania has been prepared by a sol-gel hydrothermal process. The prepared sulfated titania s...
متن کاملsulfated titania nanoparticles: an efficient catalyst for the synthesis of polyhydroquinoline derivatives through hantzsch multicomponent reaction
sulfated titania nanoparticles (so42-/tio2 nps) were synthesized using titanium tetraisopropoxide (ttip) by the sol-gel method. the structure and morphology of the prepared nanocatalyst was characterized using x-ray diffraction (xrd), scanning electron microscopy (sem) and brunauer–emmett–teller (bet) methods as well as fourier transform infrared (ft-ir) and energy dispersive x-ray (edx) spectr...
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ژورنال
عنوان ژورنال: Journal of Energy Chemistry
سال: 2015
ISSN: 2095-4956
DOI: 10.1016/s2095-4956(15)60307-2